Knowledge Management System of Northwest Institute of Plateau Biology, CAS
Acid-Catalyzed Oxidative Addition of Thiols to Olefins and Alkynes for a One-Pot Entry to Sulfoxides | |
Yue, Hui-Lan1,2; Klussmann, Martin1 | |
2016-10-01 | |
发表期刊 | SYNLETT |
卷号 | 27期号:17页码:2505-2509 |
文章类型 | Article |
摘要 | An oxidative variant of the thiol-ene reaction has been developed, achieving the direct addition of thiols to olefins to form sulfoxides. The reaction uses tert-butyl hydroperoxide as oxidant and methanesulfonic acid as catalyst. The latter is believed to catalyze the oxidation of the intermediate sulfide to the sulfoxide. No special precautions are necessary to exclude oxygen, yet the products are formed without oxidation at the -position. Styrenes, acrylic acid derivatives, alkynes, and thiophenols gave the highest yields, while aliphatic olefins and thiols were less effective. |
关键词 | Addition Homogeneous Catalysis Oxygenations Peroxides Radical Reaction Sulfoxides |
WOS标题词 | Science & Technology ; Physical Sciences |
DOI | 10.1055/s-0035-1562480 |
关键词[WOS] | SULFENATE ANIONS ; BETA-HYDROXYSULFIDES ; ENANTIOENRICHED SULFOXIDES ; PUMMERER REACTION ; ARYL SULFOXIDES ; SULFUR ; ARYLATION ; CHEMISTRY ; ALKENES ; PHARMACOPHORE |
收录类别 | SCI |
语种 | 英语 |
项目资助者 | Chinese Scholarship Council ; DFG(KL 2221/4-1) |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Organic |
WOS记录号 | WOS:000386125700020 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://210.75.249.4/handle/363003/6407 |
专题 | 中国科学院西北高原生物研究所 |
作者单位 | 1.Max Planck Inst Kohlenforsch, Kaiser Wilhelm Pl 1, D-45479 Mulheim, Germany 2.Chinese Acad Sci, Key Lab Tibetan Med Res, Northwest Inst Plateau Biol, Xining 810001, Peoples R China |
推荐引用方式 GB/T 7714 | Yue, Hui-Lan,Klussmann, Martin. Acid-Catalyzed Oxidative Addition of Thiols to Olefins and Alkynes for a One-Pot Entry to Sulfoxides[J]. SYNLETT,2016,27(17):2505-2509. |
APA | Yue, Hui-Lan,&Klussmann, Martin.(2016).Acid-Catalyzed Oxidative Addition of Thiols to Olefins and Alkynes for a One-Pot Entry to Sulfoxides.SYNLETT,27(17),2505-2509. |
MLA | Yue, Hui-Lan,et al."Acid-Catalyzed Oxidative Addition of Thiols to Olefins and Alkynes for a One-Pot Entry to Sulfoxides".SYNLETT 27.17(2016):2505-2509. |
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