Knowledge Management System of Northwest Institute of Plateau Biology, CAS
One-Pot Methylenation-Cyclization Employing Two Molecules of CO2 with Arylamines and Enaminones | |
Zhao, Yulei; Liu, Xu; Zheng, Lijun; Du, Yulan; Shi, Xinrui; Liu, Yunlin; Yan, Zhengquan; You, Jinmao![]() | |
2020 | |
发表期刊 | JOURNAL OF ORGANIC CHEMISTRY
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卷号 | 85期号:2 |
摘要 | One-pot methylenation-cyclization employing two molecules of CO2 with enaminones and primary aromatic amines was discussed for the first time to access cyclized products. This 1,5,7-triazabicyclo[4.4.0]dec-5-ene and ZnCl2-catalyzed procedure was characterized by the selective conversion of two molecules of CO2 into methylene groups in a multicomponent cyclization reaction. According to the computational study and control experiments, the reaction might proceed through the generation of bis(silyl)acetal and condensation of arylamine and aza-Diels-Alder processes. Moreover, the resulting products will probably be potential organic building blocks with adjustable photophysical properties. |
文献类型 | 期刊论文 |
条目标识符 | http://210.75.249.4/handle/363003/60437 |
专题 | 中国科学院西北高原生物研究所 |
推荐引用方式 GB/T 7714 | Zhao, Yulei,Liu, Xu,Zheng, Lijun,et al. One-Pot Methylenation-Cyclization Employing Two Molecules of CO2 with Arylamines and Enaminones[J]. JOURNAL OF ORGANIC CHEMISTRY,2020,85(2). |
APA | Zhao, Yulei.,Liu, Xu.,Zheng, Lijun.,Du, Yulan.,Shi, Xinrui.,...&Jiang, Yuanye.(2020).One-Pot Methylenation-Cyclization Employing Two Molecules of CO2 with Arylamines and Enaminones.JOURNAL OF ORGANIC CHEMISTRY,85(2). |
MLA | Zhao, Yulei,et al."One-Pot Methylenation-Cyclization Employing Two Molecules of CO2 with Arylamines and Enaminones".JOURNAL OF ORGANIC CHEMISTRY 85.2(2020). |
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