Knowledge Management System of Northwest Institute of Plateau Biology, CAS
Hydrosilane-Assisted Synthesis of Urea Derivatives from CO2 and Amines | |
Zhao, Yulei; Guo, Xuqiang; Si, Zhiyao; Hu, Yanan; Sun, Ying; Liu, Yunlin; Ji, Zhongyin; You, Jinmao | |
2020 | |
发表期刊 | JOURNAL OF ORGANIC CHEMISTRY |
卷号 | 85期号:20 |
摘要 | A methodology employing CO2, amines, and phenylsilane was discussed to access aryl- or alkyl-substituted urea derivatives. This procedure was characterized by adopting hydrosilane to promote the formation of ureas directly, without the need to prepare silylamines in advance. Control reactions suggested that FeCl3 was a favorable additive for the generation of ureas, and this 1,5,7-triazabicyclo[4.4.0] dec-5-ene-catalyzed reaction might proceed through nucleophilic addition, silicon migration, and the subsequent formal substitution of silylcarbamate. |
文献类型 | 期刊论文 |
条目标识符 | http://210.75.249.4/handle/363003/60225 |
专题 | 中国科学院西北高原生物研究所 |
推荐引用方式 GB/T 7714 | Zhao, Yulei,Guo, Xuqiang,Si, Zhiyao,et al. Hydrosilane-Assisted Synthesis of Urea Derivatives from CO2 and Amines[J]. JOURNAL OF ORGANIC CHEMISTRY,2020,85(20). |
APA | Zhao, Yulei.,Guo, Xuqiang.,Si, Zhiyao.,Hu, Yanan.,Sun, Ying.,...&You, Jinmao.(2020).Hydrosilane-Assisted Synthesis of Urea Derivatives from CO2 and Amines.JOURNAL OF ORGANIC CHEMISTRY,85(20). |
MLA | Zhao, Yulei,et al."Hydrosilane-Assisted Synthesis of Urea Derivatives from CO2 and Amines".JOURNAL OF ORGANIC CHEMISTRY 85.20(2020). |
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