Metal-Free C(sp(2))-H/N-H Cross-Dehydrogenative Coupling of Quinoxalinones with Aliphatic Amines under Visible-Light Photoredox Catalysis

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	Metal-Free C(sp(2))-H/N-H Cross-Dehydrogenative Coupling of Quinoxalinones with Aliphatic Amines under Visible-Light Photoredox Catalysis
	Wei, Wei; Wang, Leilei; Bao, Pengli; Shao, Yun; Yue, Huilan; Yang, Daoshan; Yang, Xiaobo; Zhao, Xiaohui; Wang, Hua
	2018
发表期刊	ORGANIC LETTERS
卷号	20 期号:22
摘要	A novel and efficient visible-light-induced C(sp(2))-H/N-H cross-dehydrogenative coupling (CDC)-amination with both primary and secondary aliphatic amines at room temperature in air is developed. This photocatalytic reaction allows the direct formation of 3-aminoquinoxalin-2(1H)-ones via CDC-amination in the absence of any external oxidant added from outside. Preliminary mechanistic studies reveal that the present reaction proceeds through a radical process.
文献类型	期刊论文
条目标识符	http://210.75.249.4/handle/363003/59937
专题	中国科学院西北高原生物研究所
推荐引用方式 GB/T 7714	Wei, Wei,Wang, Leilei,Bao, Pengli,et al. Metal-Free C(sp(2))-H/N-H Cross-Dehydrogenative Coupling of Quinoxalinones with Aliphatic Amines under Visible-Light Photoredox Catalysis[J]. ORGANIC LETTERS,2018,20(22).
APA	Wei, Wei.,Wang, Leilei.,Bao, Pengli.,Shao, Yun.,Yue, Huilan.,...&Wang, Hua.(2018).Metal-Free C(sp(2))-H/N-H Cross-Dehydrogenative Coupling of Quinoxalinones with Aliphatic Amines under Visible-Light Photoredox Catalysis.ORGANIC LETTERS,20(22).
MLA	Wei, Wei,et al."Metal-Free C(sp(2))-H/N-H Cross-Dehydrogenative Coupling of Quinoxalinones with Aliphatic Amines under Visible-Light Photoredox Catalysis".ORGANIC LETTERS 20.22(2018).